Biologically active polymeric materials based on water polyurethane dispersions as the agent for increase of agricultural plants productivity

Yuri V. Savelyev
Institute of Macromolecular Chemistry National Academy of Sciences of Ukraine, Kyiv, Ukraine

Galyna O. Iutynska
Zabolotny Institute of Microbiology and Virology National Academy of Scences of Ukraine, Kyiv, Ukraine

Lyudmyla P. Robota
Institute of Macromolecular Chemistry National Academy of Sciences of Ukraine, Kyiv, Ukraine

Liudmyla O. Biliavska
Zabolotny Institute of Microbiology and Virology National Academy of Scences of Ukraine, Kyiv, Ukraine

Tamara V. Travinska
Institute of Macromolecular Chemistry National Academy of Sciences of Ukraine, Kyiv, Ukraine

Olexandra M. Brykova
Institute of Macromolecular Chemistry National Academy of Sciences of Ukraine, Kyiv, Ukraine

Vladyslav I. Lytviakov
Institute of Macromolecular Chemistry National Academy of Sciences of Ukraine, Kyiv, Ukraine

Pagination: 210-225

DOI: https://doi.org/10.15407/akademperiodyka.444.210

 


Biologically active polymeric materials (BAPM) with prolonged activity have been created on the basis of ecologically safe, economically expedient water xanthan (XA)- and castor (CO)/xanthan-comprising ionomer polyurethanes (IPU) which are aggregatively stable, capable of water dilution, with the size of micelles 250-270 nm and water absorption up to 220%. IPUs of amorphous-crystalline structure (Xa- and CO/Xa-comprising) are characterized by increased degradability as compared to amorphous (CO- comprising) IPUs.  After the 12 months of incubation the weight loss of IPU / CO12 / Xa20 due to the synergistic effect of the components is 71%, while the additive contribution of the components and their total content are equaled 43.6%, 32.0%, respectively. Changing the polyether nature and/or introduction of Xa into the IPU structure allow to reduce of adhesive effects from 1.43 to 0.20 MPa, sufficient for “sticking” of BAPM on the plant surface and to reduce the surface tension, and for formation of a non-monolithic film on plant surface, and, thus, will not interfere with the activity of the plant photosynthetic apparatus. 170
         BAPM with prolonged action was obtained by chemical and physical immobilization into the IPU macrochain of the domestic polyfunctional biological product Averkom-N.  After pre-sowing treatment of seeds of grain and vegetable crops with BAPM, their growth-stimulating activity was established: an increase in biomass up to 60% compared to 40% after treatment with Averkom-N; an increase  of: tomatoes productivity (24%), average weight of fruits (30%), and a decrease of: plants’ damage by diseases in 5-8 times and the level of nitrates in comparison with Averkom-N. BAPM increase the productivity of agrophytocenoses, the resistibility of agricultural crops to abiotic and biotic stresses, yield, improve the quality of products, and improve the ecological state of the environment.


REFERENCES

 

  1. den Hond F., Groenegewegen P., van Sraalen N.M. (eds). Pesticides: Problems, Improvements, Alternatives. Oxford: Blackwell Science Ltd, Blackwell Publishing Company, 2003. 273 p.
  2. Fedotova E.N., Rysev M.N., Volkova E.S., Kustkova T.A. Efficiency of application of microbiological preparations and complex micronutrient fertilizer Aquadon-Micro in field crop rotation with fiber flax. Izvestiya Velikolukskoy gosudarstvennoy selskokhozyaystvennoy akademii. 2016. (4): 19–24. (in Russian).
  3. Grigoryuk I.P., Savel’ev Yu.V., Mashkovska S.P., Levchenko N.I. Nikolaichuk V.I. The efficiency of the ionomeric polyurethanes on the photosynthetic apparatus and the production of winter wheat for the dry land. Scientific bulletin of the Uzhhorod University. Ser. Biology. 2003. (12): 73–81. (in Ukrainian).
  4. Patent of Ukraine No. 93372. Savel’ev Yu.V., Travinska T.V., Markovska L.A., Brikova O.M. The way of rejecting polymeric biodestructive compositions. Publ. 25.09.2014. Bul. No. 18.
  5. Ermolovich O.A., Makarevich A.V., Goncharova E.P. Methods for analyzing of biodegrability of polymeric materials. Biotekhnologiya. 2005. (4): 47–54. (in Russian).
  6. Travinskaya T.V., Brykova A.N.,Savelyev Yu.V. Degradable ionic polyurethanes based on vegetable oil and polysaccharide: preparation and properties. Dopov. Nac. Akad. Nauk Ukr. 2016. (12): 82–89. https://doi.org/10.15407/dopovidi2016.12.082
  7. Travinskaya T.V., Brykova A.N., Savelyev Yu.V., Lebedev E.V. Anion-active polyurethanes with increased content of renewable raw materials. Dopov. Nac. Akad. Nauk Ukr. 2018. (11): 76–83. https://doi.org/10.15407/dopovidi2018.11.076
  8. Sonntag N.O.V. Glycerolysis of fats and methyl esters — status, review and critique. J. Am. Oil Chem. Soc. 1982. 59(10): 795–802. https://doi.org/10.1007/BF02634442
  9. Robota L.P., Travinskaya T.V., Shtompel V.I., Brykova A.N., Savelyev Yu.V. Structure of the polyurethane ionomers containing natural compounds. Polymer Journal. 2016. 38(4): 185–191. https://doi.org/10.15407/polymerj.38.04.312
  10. Dyatlova K.D. Microbial preparations in plant growing. Sorosovskiy obrazovatelnyy zhurnal. 2001. 7(5): 17–22. (in Russian).
  11. Patent of Ukraine No. 69639. Iutinskaya G.O., Koziritska V.Y., Valagurova O.V., Mukvich M.S., Bilyavska L.O., Petruk T.V. Streptomyces avermitilis strain — producer of avermect-niv, antiparasitic rechovin. Publ. 15.08.06. Bul. No. 8.
  12. Patent of Ukraine No. 145127. Savel’ev Yu.V., Brikova O.M., Travinska T.V., Robota L.P., Markovska L.A., Iutinska G.O., Bilyavska L.O. Polymeric composition. Publ. 11.25.2020. Bul. No. 22.
  13. GOST 8756.13. Products of processing of fruits and vegetables. Methods for the determination of sugars. Moscow: Publishing house of standards, 1987. (in Russian).