{"id":1523,"date":"2022-01-23T11:22:56","date_gmt":"2022-01-23T11:22:56","guid":{"rendered":"https:\/\/akademperiodyka.org.ua\/en\/?page_id=1523"},"modified":"2022-01-23T11:29:05","modified_gmt":"2022-01-23T11:29:05","slug":"design-of-functional-nanocomposites-based-on-graphene-and-graphene-like-materials-as-well-as-organic-conjugated-polymers-promising-electrode-materials-for-supercapacitors-and-heterogeneous","status":"publish","type":"page","link":"https:\/\/akademperiodyka.org.ua\/en\/books\/pavl\/1\/","title":{"rendered":"Design of functional nanocomposites based on graphene and graphene-like materials, as well as organic conjugated polymers \u2013 promising electrode materials for supercapacitors and heterogeneous catalysts"},"content":{"rendered":"
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Yaroslav I. Kurys<\/div>\n
L.V.<\/em> Pisa<\/em>rzhevsk<\/em>ii Institute of Physical Chemistry of the National Academy of Sciences of Ukraine, Kyiv, Ukraine<\/em><\/div>\n
ORCID:\u00a0https:\/\/orcid.org\/0000-0002-7088-6324<\/a><\/div>\n
Scopus Author ID: https:\/\/www.scopus.com\/authid\/detail.uri?authorId=6508014496<\/a><\/div>\n<\/div>\n<\/div>\n<\/div>\n<\/div>\n
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Olha A. Kozarenko<\/div>\n
L.V.<\/em> Pisa<\/em>rzhevsk<\/em>ii Institute of Physical Chemistry of the National Academy of Sciences of Ukraine, Kyiv, Ukraine<\/em><\/div>\n
Scopus Author ID: https:\/\/www.scopus.com\/authid\/detail.uri?authorId=36668746100<\/a><\/div>\n<\/div>\n<\/div>\n<\/div>\n<\/div>\n
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Vyacheslav G. Koshechko<\/div>\n
L.V.<\/em> Pisa<\/em>rzhevsk<\/em>ii Institute of Physical Chemistry of the National Academy of Sciences of Ukraine, Kyiv, Ukraine<\/em><\/div>\n
Scopus Author ID: https:\/\/www.scopus.com\/authid\/detail.uri?authorId=35617865700<\/a><\/div>\n<\/div>\n<\/div>\n<\/div>\n<\/div>\n
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Vitaly D. Pokhodenko<\/div>\n
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DOI:<\/strong> https:\/\/doi.org\/10.15407\/akademperiodyka.444.011<\/a><\/p>\n

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Abstract<\/h2>\n

The results obtained during the project on the development of promising functional nanocomposites based on graphene and graphene-like materials, as well as conducting polymers as active electrode materials for symmetric supercapacitors (SSC) and heterogeneous catalysts for quinoline hydrogenation are considered. Using a mechanochemical approach, nanocomposites based on polyaniline (PAni) and a number of 2D materials (nanostructured graphite \u2013 nG, molybdenum disulfide \u2013 nMoS2<\/sub>, tungsten disulfide \u2013 nWS2<\/sub>) were obtained. It was found that PAni\/nG-based electrodes are able to provide the specific capacity of ~360 F\/g in SSC and stability for at least 10,000 charge-discharge cycles. It is shown that PAni\/nG-based SSC is able to operate at high current and the specific power of SSC can reach ~10 kW\/kg at the specific energy of ~18 W\u2219h\/kg. In the study of SSC based on nMoS2<\/sub>\/PAni and nWS2<\/sub>\/PAni, it was found that nanoparticles of d-metal sulfides to promote electrochemical reversibility of redox conversion in PAni at high potentials and contribute to the stability of nanocomposites during prolonged charge-discharge cycling. The specific capacity of such materials can reach 610 F\/g and the specific power of SSC can reach ~4.1 kW\/kg for specific energy ~23.5 W\u00b7h\/kg. A number of Co-containing nanocomposites consisting of Co9<\/sub>S8<\/sub> particles on Co,N,S-doped carbon was obtained by pyrolysis using various nanosized carbon materials and the monomer (5-aminoindole) – oxidant (ammonium persulfate) system. High catalytic activity of the obtained nanocomposites in the quinoline hydrogenation reaction was demonstrated \u2013 the yield of the target product (1,2,3,4-tetrahydroquinoline) is from ~85-90% to almost quantitative.<\/p>\n<\/div>\n<\/div>\n<\/div>\n<\/div>\n

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REFERENCES<\/strong><\/p>\n

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    Yaroslav I. Kurys L.V. Pisarzhevskii Institute of Physical Chemistry of the National Academy of Sciences of Ukraine, Kyiv, Ukraine ORCID:\u00a0https:\/\/orcid.org\/0000-0002-7088-6324 Scopus Author ID: https:\/\/www.scopus.com\/authid\/detail.uri?authorId=6508014496 Olha A. Kozarenko L.V. Pisarzhevskii Institute of Physical Chemistry of the National Academy of Sciences of Ukraine, Kyiv, Ukraine Scopus Author ID: https:\/\/www.scopus.com\/authid\/detail.uri?authorId=36668746100 Vyacheslav G. Koshechko L.V. Pisarzhevskii Institute of Physical […]<\/p>\n","protected":false},"author":1,"featured_media":0,"parent":0,"menu_order":85,"comment_status":"closed","ping_status":"closed","template":"","meta":{"footnotes":""},"class_list":["post-1523","page","type-page","status-publish","hentry"],"_links":{"self":[{"href":"https:\/\/akademperiodyka.org.ua\/en\/wp-json\/wp\/v2\/pages\/1523","targetHints":{"allow":["GET"]}}],"collection":[{"href":"https:\/\/akademperiodyka.org.ua\/en\/wp-json\/wp\/v2\/pages"}],"about":[{"href":"https:\/\/akademperiodyka.org.ua\/en\/wp-json\/wp\/v2\/types\/page"}],"author":[{"embeddable":true,"href":"https:\/\/akademperiodyka.org.ua\/en\/wp-json\/wp\/v2\/users\/1"}],"replies":[{"embeddable":true,"href":"https:\/\/akademperiodyka.org.ua\/en\/wp-json\/wp\/v2\/comments?post=1523"}],"version-history":[{"count":6,"href":"https:\/\/akademperiodyka.org.ua\/en\/wp-json\/wp\/v2\/pages\/1523\/revisions"}],"predecessor-version":[{"id":1529,"href":"https:\/\/akademperiodyka.org.ua\/en\/wp-json\/wp\/v2\/pages\/1523\/revisions\/1529"}],"wp:attachment":[{"href":"https:\/\/akademperiodyka.org.ua\/en\/wp-json\/wp\/v2\/media?parent=1523"}],"curies":[{"name":"wp","href":"https:\/\/api.w.org\/{rel}","templated":true}]}}