{"id":1634,"date":"2022-01-23T16:04:22","date_gmt":"2022-01-23T16:04:22","guid":{"rendered":"https:\/\/akademperiodyka.org.ua\/en\/?page_id=1634"},"modified":"2022-01-23T16:05:56","modified_gmt":"2022-01-23T16:05:56","slug":"development-of-the-new-generation-catalysts-for-the-process-of-bioethanol-conversion-into-13-butadiene-for-further-synthesis-of-reactive-oligomers-as-the-binding-agents-for-high-energy-compositions","status":"publish","type":"page","link":"https:\/\/akademperiodyka.org.ua\/en\/books\/pavl\/20\/","title":{"rendered":"Development of the new generation catalysts for the process of bioethanol conversion into 1,3-butadiene for further synthesis of reactive oligomers as the binding agents for high-energy compositions"},"content":{"rendered":"
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Sergiy O. Soloviev<\/div>\n
L.V. Pisarzhevskii Institute of Physical Chemistry, The National Academy of Sciences of Ukraine, Kyiv, Ukraine<\/em>.<\/div>\n
ORCID: https:\/\/orcid.org\/0000-0001-9271-7495<\/a><\/div>\n
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Pavlo I. Kyriienko<\/div>\n
L.V. Pisarzhevskii Institute of Physical Chemistry, The National Academy of Sciences of Ukraine, Kyiv, Ukraine.<\/em><\/div>\n
ORCID: https:\/\/orcid.org\/0000-0003-1533-3492<\/a><\/div>\n
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Olga V. Larina<\/div>\n
L.V. Pisarzhevskii Institute of Physical Chemistry, The National Academy of Sciences of Ukraine, Kyiv, Ukraine.<\/em><\/div>\n
ORCID: https:\/\/orcid.org\/0000-0001-6359-1512<\/a><\/div>\n
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Nataliia V. Hudzenko<\/div>\n
Institute of Macromolecular Chemistry the National Academy of Sciences of Ukraine, Kyiv, Ukraine\u00a0\u00a0<\/em><\/div>\n
ORCID:\u00a0https:\/\/orcid.org\/0000-0003-2363-4527<\/a><\/div>\n
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Vitaly P.\u00a0Boiko<\/div>\n
Institute of Macromolecular Chemistrythe National Academy of Sciences of Ukraine, Kyiv, Ukraine\u00a0\u00a0<\/em><\/div>\n
ORCID:\u00a0https:\/\/orcid.org\/0000-0002-0157-6664<\/a><\/div>\n
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Vladimir K. Grishchenko<\/div>\n
Institute of Macromolecular Chemistry\u00a0the National Academy of Sciences of Ukraine, Kyiv, Ukraine\u00a0\u00a0<\/em><\/div>\n
ORCID:\u00a0https:\/\/orcid.org\/0000-0002-4951-936\u0425<\/a><\/div>\n
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Pagination: 268-279<\/div>\n

DOI: https:\/\/doi.org\/10.15407\/akademperiodyka.444.268<\/a><\/p>\n<\/div>\n<\/div>\n<\/div>\n<\/div>\n

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The influence of composition of ZnO(Cu)\/MgO-SiO2<\/sub> and ZnO(Cu)\/ZrO2<\/sub>-SiO2<\/sub> catalysts on their catalytic performance in the 1,3-butadiene production process from rectified ethanol and ethanol-aqueous mixtures has been studied.<\/div>\n
The ZnO\/MgO-SiO2<\/sub> catalyst that contains equivalent amounts of MgO and SiO2<\/sub>, is characterized by the highest activity and selectivity for 1,3-butadiene among ZnO\/MgO-SiO2<\/sub> systems, due to the optimal ratio of acid and basic surface sites. It is shown that highly active MgO-SiO2<\/sub>-based catalysts can be obtained by wet-kneading of magnesium oxide\/hydroxide and freshly precipitated silicate material, due to which it is possible to obtain a high concentration of LAS in interface of the components. Catalysts ZnO\/ZrO2<\/sub>-SiO2<\/sub> prepared by wet-kneading of ZnO nanoparticles and ZrO2<\/sub>-SiO2<\/sub> has shown higher activity and selectivity in the conversion of ethanol-water mixtures into 1,3-butadiene compared to those prepared by impregnation.<\/div>\n
It has been shown that the radical polymerization of the C4<\/sub> fraction obtained by the catalytic conversion of ethanol\/ethanol-aqueous mixtures makes it possible to obtain functionalized liquid rubbers that can be used as binders in the creation of high-energy compositions for various purposes.<\/div>\n<\/div>\n<\/div>\n<\/div>\n<\/div>\n
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Sergiy O. Soloviev L.V. Pisarzhevskii Institute of Physical Chemistry, The National Academy of Sciences of Ukraine, Kyiv, Ukraine. ORCID: https:\/\/orcid.org\/0000-0001-9271-7495 Pavlo I. Kyriienko L.V. Pisarzhevskii Institute of Physical Chemistry, The National Academy of Sciences of Ukraine, Kyiv, Ukraine. ORCID: https:\/\/orcid.org\/0000-0003-1533-3492 Olga V. Larina L.V. Pisarzhevskii Institute of Physical Chemistry, The National Academy of Sciences of […]<\/p>\n","protected":false},"author":1,"featured_media":0,"parent":0,"menu_order":80,"comment_status":"closed","ping_status":"closed","template":"","meta":{"footnotes":""},"class_list":["post-1634","page","type-page","status-publish","hentry"],"_links":{"self":[{"href":"https:\/\/akademperiodyka.org.ua\/en\/wp-json\/wp\/v2\/pages\/1634","targetHints":{"allow":["GET"]}}],"collection":[{"href":"https:\/\/akademperiodyka.org.ua\/en\/wp-json\/wp\/v2\/pages"}],"about":[{"href":"https:\/\/akademperiodyka.org.ua\/en\/wp-json\/wp\/v2\/types\/page"}],"author":[{"embeddable":true,"href":"https:\/\/akademperiodyka.org.ua\/en\/wp-json\/wp\/v2\/users\/1"}],"replies":[{"embeddable":true,"href":"https:\/\/akademperiodyka.org.ua\/en\/wp-json\/wp\/v2\/comments?post=1634"}],"version-history":[{"count":4,"href":"https:\/\/akademperiodyka.org.ua\/en\/wp-json\/wp\/v2\/pages\/1634\/revisions"}],"predecessor-version":[{"id":1638,"href":"https:\/\/akademperiodyka.org.ua\/en\/wp-json\/wp\/v2\/pages\/1634\/revisions\/1638"}],"wp:attachment":[{"href":"https:\/\/akademperiodyka.org.ua\/en\/wp-json\/wp\/v2\/media?parent=1634"}],"curies":[{"name":"wp","href":"https:\/\/api.w.org\/{rel}","templated":true}]}}