{"id":2006,"date":"2022-01-25T11:29:13","date_gmt":"2022-01-25T11:29:13","guid":{"rendered":"https:\/\/akademperiodyka.org.ua\/en\/?p=2006"},"modified":"2026-04-06T20:07:04","modified_gmt":"2026-04-06T20:07:04","slug":"ratishvili","status":"publish","type":"post","link":"https:\/\/akademperiodyka.org.ua\/en\/books\/ratishvili\/","title":{"rendered":"Effects of Atomic Ordering of Interstitial Hydrogen on the Physical Properties of Host Metals"},"content":{"rendered":"
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Authors:<\/strong><\/div>\n<\/div>\n
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Ratishvili I.G.<\/div>\n
Tatarenko\u00a0 V.A<\/div>\n
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Year:<\/strong> 2021<\/div>\n<\/div>\n
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Pages:<\/strong> 146<\/div>\n<\/div>\n
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ISBN:<\/strong> 978-966-360-448-0<\/div>\n<\/div>\n
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Publication Language:<\/strong> English<\/div>\n<\/div>\n
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Edition:<\/strong> 150<\/div>\n<\/div>\n
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Publisher:<\/strong> PH \u201cAkademperiodyka\u201d<\/div>\n<\/div>\n
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Place Published:<\/strong> Kyiv<\/div>\n<\/div>\n
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DOI:<\/strong> https:\/\/doi.org\/10.15407\/akademperiodyka.448.146<\/a><\/div>\n<\/div>\n
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Web of Science Core Collection: <\/strong>https:\/\/www.webofscience.com\/wos\/woscc\/full-record\/WOS:001521432300012<\/a><\/div>\n<\/div>\n<\/div>\n
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Physicochemical data on the influence of interstitial atoms of hydrogen isotopes on the properties of face-centred cubic, body-centred cubic and hexagonal close-packed metals are reviewed on the basis of statistical thermodynamic theory of long- and short-range atomic order. Examples of the application of metal\u2014hydrogen alloys are given.<\/p>\n

This brochure is intended for physical materials science specialists. It can be useful for both postgraduate students and lecturers of universities of engineering-physical specialties.<\/p>\n<\/div>\n<\/div>\n<\/div>\n<\/div>\n

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REFERENCES:<\/strong><\/p>\n

Part I<\/strong><\/p>\n

    \n
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  33. V.E. Antonov, T.E. Antonova, I.T. Belash, O.V. Jarikov, A.I. Latinin, A.V. Palnichenko, V.I. Raschupkin. ‘Superconductivity of the solid solutions of hydrogen in the compounds Nb3 M with a structure A-15 (M = Au, Pt, Ir, Os)’. Fiz. Tverd. Tela, 31, No. 10: 12-20 (1989) (in Russian).<\/li>\n
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  35. I.G. Ratishvili, P. Vajda, N.Z. Namoradze. ‘Heat capacity associated with hydrogen ordering in superstoichiometric rare-earth dihydrides: the case of LaH2+x-like systems’. J. Phys. Chem. Sol., 58, No. 1: 59-62 (1997). https:\/\/doi.org\/10.1016\/S0022-3697(96)00102-3<\/a><\/li>\n
  36. I.G. Ratishvili, N.Z. Namoradze. ‘Heat capacity associated with hydrogen ordering in superstoichiometric rare-earth dihydrides. CeH2+x-like systems’. Bull. Georg. Acad. Sci., 158: 229-232 (1998).<\/li>\n
  37. Z. Bieganski, W. Fesenko, B. Stalinski. ‘Low-temperature heat capacity of cerium trihydride. Crustal field effects in rare-earth hydrides. II’. Bull. Acad. Polon. Sci. Ser. Sci. Chim., XIII, No. 3: 227-230 (1965).<\/li>\n
  38. N. Namoradze, I. Ratishvili. ‘Ordering effects in the heat capacity of light rare-earth superstoichiometric dihydrides. CeH2.86. Bull. Georgia Nat. Acad. Sci., 6, No. 2: 51-54 (2012).<\/li>\n
  39. I.G. Ratishvili. ‘Phase transition type change in order-order and order-disorder transformations of LaH2+c-like superstoichiometric dihydrides’. phys. status solid (b), 213: 297-315 (1999). https:\/\/doi.org\/10.1002\/(SICI)1521-3951(199906)213:2<297::AID-PSSB297>3.0.CO;2-0<\/a><\/li>\n
  40. I.G. Ratishvili, N.Z. Namoradze. ‘Heat capacity anomalies associated with phase transition type change in CeH2+x-like superstoichiometric rare-earth dihydrides’. J. Phys. Chem. Sol., 61: 1827-1838 (2000). https:\/\/doi.org\/10.1016\/S0022-3697(00)00063-9<\/a><\/li>\n
  41. I.G. Ratishvili, N.Z. Namoradze. ‘Heat capacity anomalies associated with phase transition type change in LaH2+x-like superstoichiometric rare-earth dihydrides’. phys. status solidi (b), 225: 1-14 (2001). https:\/\/doi.org\/10.1002\/(SICI)1521-3951(200105)225:1<1::AID-PSSB1>3.0.CO;2-W<\/a><\/li>\n
  42. I.G. Ratishvili, N.Z. Namoradze. ‘Change in the order of the phase transition in ordering rareearth hydrides: a heat capacity anomaly’. Th e Physics of Metals and Metallography, 89, No. 2: 145-149 (2000).<\/li>\n
  43. J.M. Rowe. ‘A neutron scattering study of the vibrational and diffusional motions of deuterium in the \u03b1 and \u03b2 phases of VD0.5’. Solid State Commun., 11: 1299-1302 (1972). https:\/\/doi.org\/10.1016\/0038-1098(72)90847-2<\/a><\/li>\n
  44. N.Z. Namoradze, I.G. Ratishvili. ‘Influence of interstitial atoms on the heat capacity of the host metal lattice’. Metallofi z. Noveishie Tekhnol., 31, No. 6: 869-875 (2009).<\/li>\n
  45. I.G. Ratishvili, N.Z. Namoradze. ‘Temperature dependence of hydrogen mobility in ordering rare-earth dihydrides’. Bull. Georg. Nat. Acad. Sci., 3, No. 3: 70-75 (2009).<\/li>\n
  46. I.G. Ratishvili, N.Z. Namoradze. ‘Temperature dependence of local mode frequencies in ordering metal hydrides. The case of b.c.c. metal lattices’. Metallofi z. Noveishie Tekhnol., 33, No. 7: 919-936 (2011).<\/li>\n
  47. N.Z. Namoradze, I.G. Ratishvili. ‘The particle weighting effect in the heat capacity temperature dependence of the V2 D ordering interstitial alloys’. Metallofiz. Noveishie Tekhnol., 39, No. 5: 579-511 (2017). https:\/\/doi.org\/10.15407\/mfint.39.05.0579<\/a><\/li>\n
  48. R.M. Cotts. ‘Nuclear magnetic resonance on metal-hydrogen systems’. In: ‘Hydrogen in Metals I’ (eds. G. Alefeld, J. V\u00f6lkl) (Berlin: Springer-Verlag: 1964), pp. 227-288. https:\/\/doi.org\/10.1007\/3540087052_48<\/a><\/li>\n
  49. Y. Fukai, S. Kazama. ‘NMR studies of anomalous diffusion of hydrogen and phase transition in vanadium-hydrogen alloys’. Acta Metall., 25, No. 1: 59-70 (1977). https:\/\/doi.org\/10.1016\/0001-6160(77)90246-2<\/a><\/li>\n
  50. R.G. Barns. In: ‘Hydrogen in Metalls III’ (ed. H. Wipf) (Berlin-Heidelberg-New York: SpringerVerlag: 1995), pp. 93-151.<\/li>\n
  51. Y. Fukai. ‘The Metal-Hydrogen System: Basic Bulk Properties’ (Springer series in materials science, vol. 21) (Berlin-Heidelberg-New York: Springer-Verlag: 1993). https:\/\/doi.org\/10.1007\/978-3-662-02801-8<\/a><\/li>\n
  52. I.G. Ratishvili, N.Z. Namoradze. ‘Influence of hydrogen ordering on the spin-lattice relaxation time in metal-hydrides. I. The high-temperature limit’. Bull. Georg. Acad. Sci., 169, No. 2: 279- 281 (2004).<\/li>\n
  53. I.G. Ratishvili, N.Z. Namoradze. ‘Influence of hydrogen ordering on the spin-lattice relaxation time in metal-hydrides. II. The low-temperature limit’. Bull. Georg. Acad. Sci., 169, No. 3: 481- 483 (2004).<\/li>\n
  54. N.Z. Namoradze, I.G. Ratishvili. ‘Influence of hydrogen ordering on the proton spin-lattice relaxation time in lanthanum superstoichiometric dihydrides LaH2+c’. In: ‘Hydrogen Materials Science and Chemistry of Carbon Nanomaterials’ (eds. T.N. Veziroglu, S.Y. Zaginaichenko, D.V. Schur, B. Baranowski, A.P. Shpak, V.V. Skorokhod, A. Kale) (Dordrecht, Netherlands: Springer: 2007), pp. 87-94; https:\/\/doi.org\/10.1007\/978-1-4020-5514-0<\/a><\/li>\n
  55. I.G. Ratishvili, N.Z. Namoradze. ‘Temperature dependence of hydrogen mobility in the ordering rare-earth dihydrides’. Bull. Georg. Nat. Acad. Sci., 3, No. 3: 70-75 (2009).<\/li>\n
  56. T.-T. Phua, B.J. Beaudry, D.T. Peterson, D.R. Torgeson, R.G. Barns, M. Belhoul, G.A. Styles, E.F.W. Seymour. ‘Paramagnetic impurity effects in NMR determinations of hydrogen diffusion and electronic structure in metal hydrides: Gd3+ in YH2 and LaH2.25’. Phys. Rev., 28, No. 11: 6227 (1983).<\/li>\n
  57. G.I. Mamniashvili, N.Z. Namoradze, I.G. Ratishvili, Yu.G. Sharimanov. ‘Proton spin-lattice relaxation time in ordering VHx alloys’. J. Phys. Chem. Solids, 66: 1192-1199 (2005). https:\/\/doi.org\/10.1016\/j.jpcs.2005.01.011<\/a><\/li>\n
  58. I. Ratishvili, N. Namoradze. ‘Physical properties of some metal hydrides applicable for hydrogen detectors: brief review’. In: ‘Black See Energy Resource Development and Hydrogen Energy Problems’ (eds. Ayfer Veziro\u011flu, M. Tsitskishvili) (Dordrecht, Netherlands: Springer: 2013), ch. 32, pp. 373-389; https:\/\/doi.org\/10.1007\/978-94-007-6152-0<\/a><\/li>\n
  59. N.Z. Namoradze, I.G. Ratishvili. ‘Hydrogen ordering induced resistivity anomalies in the superstoichiometric light rare-earth dihydrides’. J. Alloys Comp., 446-447: 429-435 (2007). https:\/\/doi.org\/10.1016\/j.jallcom.2006.12.005<\/a><\/li>\n
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  62. A.A. Smirnov. ‘Theory of Electrical Resistivity of Alloys’ (Kiev: AS of the Ukr. SSR Publishing: 1960). 148 p. (in Russian)<\/li>\n
  63. P. Vajda, J.N. Daou. Mod. Phys. Lett. B, 6: 251 (1992). https:\/\/doi.org\/10.1142\/S0217984992000338<\/a><\/li>\n
  64. J.N. Daou, A. Loucasson, P. Vajda, J.P. Burger. J. Phys. F: Met. Phys., 14: 2983 (1984). https:\/\/doi.org\/10.1088\/0305-4608\/14\/12\/019<\/a><\/li>\n
  65. A. Loucasson, P. Vajda, J.P. Burger, J.N. Daou. Sol. State Commun., 54: 807-810 (1985). https:\/\/doi.org\/10.1016\/0038-1098(85)90291-1<\/a><\/li>\n
  66. H. L\u00fctgemeier, R.R. Arons, H.G. Bohn. ‘Proton spin-lattice relaxation time in niobiumhydrogen system’. J. Magn. Reson., 8: 74-79 (1972). https:\/\/doi.org\/10.1016\/0022-2364(72)90024-8<\/a><\/li>\n
  67. Yu.G. Sharimanov, R. Grossescu. ‘Temperature dependence of pronon spin-lattice relaxation time in the niobium hydride’. Fiz. Tverd. Tela, 24, No. 1: 310-311 (1982) (in Russian).<\/li>\n
  68. M.A. Pick, R. Baush. ‘The determination of the force-dipole tensor of hydrogen in niobium’. J. Phys. F: Metal Phys., 6, No. 10: 1751-1763 (1976). https:\/\/doi.org\/10.1088\/0305-4608\/6\/10\/008<\/a><\/li>\n
  69. I. Ratishvili, N. Namoradze. ‘Switchable magnetic properties of hydrogenated metal alloys’. In: ‘Progress in Clean Energy’ (Cham, Switzerland: Springer: 2015) (eds. I. Dincer, I. Dincer, C. Colpan, O. Kizilkan, M. Ezan), vol. 1. ch. 55, pp. 751-761; https:\/\/doi.org\/10.1007\/978-3- 319-16709-1_55<\/a><\/li>\n
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  71. I.G. Ratishvili. ‘The orientational model of hydrides ordering’. Fiz. Met. Metalloved., 1991, No. 10: 74-86 (in Russian).<\/li>\n
  72. N.Z. Namoradze, I.G. Ratishvili. ‘Formation of linear structures in metal-hydrogen interstitial alloys’. In: ‘Carbon Nanomaterials in Clean Energy Hydrogen Systems’ (eds. B. Baranowski, S.Yu. Zaginaichenko, D.V. Schur, V.V. Skorokhod, Ayfer Veziroglu) (Dordrecht, Netherlands: Springer: 2008), pp. 549-572; https:\/\/doi.org\/10.1007\/978-1-4020-8898 -8<\/a><\/li>\n<\/ol>\n

    Part II <\/strong><\/p>\n

      \n
    1. M.A. Krivoglaz, Difraktsiia Rentgenovskikh Luche\u012d i Ne\u012dtronov v Neideal’nykh Kristallakh (X-Ray and Neutron Diffraction in Nonideal Crystals) (Kiev: Naukova Dumka: 1983) (in Russian).<\/li>\n
    2. M.A. Krivoglaz, Diffuznoye Rasseianie Rentgenovskikh Luche\u012d i Ne\u012dtronov na Fluktuatsionnykh Neodnorodnostiakh v Neideal’nykh Kristallakh (Diffuse Scattering of X-Rays and Neutrons on Fluctuation Heterogeneities in Nonideal Crystals) (Kyiv: Naukova Dumka: 1984) (in Russian).<\/li>\n
    3. A.G. Khachaturyan. Phys. Status Solidi (b), 60: 9 (1973). https:\/\/doi.org\/10.1002\/pssb.2220600102<\/a><\/li>\n
    4. A.G. Khachaturyan, B.I. Pokrovskii, Progress in Materials Science, 29, Iss. 1-2: 1 (1985); https:\/\/doi.org\/10.1016\/0079-6425(85)90008-8<\/a><\/li>\n
    5. A.G. Khachaturyan, Theory of Structural Transformations in Solids (Mineola, NY: Dover Publications, Inc.: 2008).<\/li>\n
    6. K.H. Jack, Acta Cryst., 5: 404 (1952). https:\/\/doi.org\/10.1107\/S0365110X52001258<\/a><\/li>\n
    7. M. Hirabayashi, S. Yamaguchi, H. Asano, K. Hiraga, Reine und Angew. Metall. Einzeldarstel. (ed. H. Warlimont) (Berlin: Springer-Verlag: 1974), vol. 24, p. 206.<\/li>\n
    8. V. Seetharaman, D. Sundararaman, Mater. Sci. Forum, 3: 433 (1985). https:\/\/doi.org\/10.4028\/www.scientific.net\/MSF.3.433<\/a><\/li>\n
    9. S.I. Morozov, Issledovanie Primesnykh Kolebaniy Atomov Vnedreniya v Tsirkonii i Titane Metodom Neuprugogo Rasseyaniya Medlennykh Neutronov (Study of Impurity Oscillations of Interstitial Atoms in Zirconium and Titanium by the Method of Inelastic Scattering of Slow Neutrons) (Abstract of a Thesis for Cand. Phys.-Math. Sci.) (Obninsk: Physical-Energetic Inst.: 1989) (in Russian).<\/li>\n
    10. V.N. Bugaev, V.A. Tatarenko, Vzaimodeistvie i Raspredelenie Atomov v Splavakh Vnedreniya na Osnove Plotnoupakovannykh Metallov (Interaction and Arrangement of Atoms in Interstitial Alloys Based on Close-Packed Metals) (Kyiv: Naukova Dumka: 1989) (in Russian).<\/li>\n
    11. V.A. Tatarenko, C.L. Tsinman, Metallofi z. Noveishie Tekhnol., 19, No. 11: 9 (1997) (in Russian).<\/li>\n
    12. P.V. Gel’d, R.A. Ryabov, L.P. Mokhracheva, Vodorod i Fizicheskie Svoistva Metallov i Splavov (Hydrogen and Physical Properties of Metals and Alloys) (Moscow: Nauka: 1985) (in Russian).<\/li>\n
    13. R.A. Andrievskiy, Ya.S. Umanskiy, Fazy Vnedreniya (Interstitial Phases) (Moscow: Nauka: 1977) (in Russian).<\/li>\n
    14. E. Fromm, E. Gebhardt, Gase und Kohlenstoff in Metallen (Gases and Carbon in Metals). 26 Band (Berlin-Heidelberg: Springer-Verlag: 1976) (in German). https:\/\/doi.org\/10.1007\/978-3-642-80943-9<\/a><\/li>\n
    15. G. Leibfried, Mikroskopicheskaya Teoriya Mekhanicheskikh i Teplovykh Svoistv Kristallov (Microscopic Theory of Mechanical and Thermal Properties of Crystals) (Moscow-Leningrad: Fizmatgiz: 1963) (Russian translation).<\/li>\n
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         <\/p>\n

         <\/p>\n

         <\/p>\n","protected":false},"excerpt":{"rendered":"

        Authors: Ratishvili I.G. Tatarenko\u00a0 V.A Year: 2021 Pages: 146 ISBN: 978-966-360-448-0 Publication Language: English Edition: 150 Publisher: PH \u201cAkademperiodyka\u201d Place Published: Kyiv DOI: https:\/\/doi.org\/10.15407\/akademperiodyka.448.146 Web of Science Core Collection: https:\/\/www.webofscience.com\/wos\/woscc\/full-record\/WOS:001521432300012 Physicochemical data on the influence of interstitial atoms of hydrogen isotopes on the properties of face-centred cubic, body-centred cubic and hexagonal close-packed metals are reviewed […]<\/p>\n","protected":false},"author":1,"featured_media":2007,"comment_status":"closed","ping_status":"open","sticky":false,"template":"","format":"standard","meta":{"footnotes":""},"categories":[4,21,24],"tags":[],"class_list":["post-2006","post","type-post","status-publish","format-standard","has-post-thumbnail","hentry","category-books","category-scientific_monographs","category-ukrainian_scientifical_book"],"_links":{"self":[{"href":"https:\/\/akademperiodyka.org.ua\/en\/wp-json\/wp\/v2\/posts\/2006","targetHints":{"allow":["GET"]}}],"collection":[{"href":"https:\/\/akademperiodyka.org.ua\/en\/wp-json\/wp\/v2\/posts"}],"about":[{"href":"https:\/\/akademperiodyka.org.ua\/en\/wp-json\/wp\/v2\/types\/post"}],"author":[{"embeddable":true,"href":"https:\/\/akademperiodyka.org.ua\/en\/wp-json\/wp\/v2\/users\/1"}],"replies":[{"embeddable":true,"href":"https:\/\/akademperiodyka.org.ua\/en\/wp-json\/wp\/v2\/comments?post=2006"}],"version-history":[{"count":12,"href":"https:\/\/akademperiodyka.org.ua\/en\/wp-json\/wp\/v2\/posts\/2006\/revisions"}],"predecessor-version":[{"id":7849,"href":"https:\/\/akademperiodyka.org.ua\/en\/wp-json\/wp\/v2\/posts\/2006\/revisions\/7849"}],"wp:featuredmedia":[{"embeddable":true,"href":"https:\/\/akademperiodyka.org.ua\/en\/wp-json\/wp\/v2\/media\/2007"}],"wp:attachment":[{"href":"https:\/\/akademperiodyka.org.ua\/en\/wp-json\/wp\/v2\/media?parent=2006"}],"wp:term":[{"taxonomy":"category","embeddable":true,"href":"https:\/\/akademperiodyka.org.ua\/en\/wp-json\/wp\/v2\/categories?post=2006"},{"taxonomy":"post_tag","embeddable":true,"href":"https:\/\/akademperiodyka.org.ua\/en\/wp-json\/wp\/v2\/tags?post=2006"}],"curies":[{"name":"wp","href":"https:\/\/api.w.org\/{rel}","templated":true}]}}